Matthew Perry, who played Chandler Bing on Friends, has revealed in his new memoir, Friends, Lovers and the Big Terrible Thing, that he had a crush on co-star Jennifer Aniston, who played Rachel Green. Perry explained that he had asked Aniston out before they started working together but was declined and ended up blurting out "We can't be friends!" when she suggested they stay friends. Despite this awkward encounter, they became close friends while working on the show. The revelation adds to the enduring legacy of Friends and its beloved cast of characters.